Thermal Characterization of Polyurethane Acrylate Resins |
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Authors: | Ledru J Saiter J M Grenet J Youssef B Burel F Bunel C |
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Institution: | (1) Laboratoire d'Etude et de Caractérisation des Amorphes et des Polymeres, EA 1292, Faculté des Sciences, Universite de Rouen, 76821 Mont-Saint-Aignan Cedex, France;(2) Laboratoire des Materiaux Macromoléculaires, Institut National des Sciences Appliquées de Rouen, Place Emile Blondel, BP 08, 76131 Mont-Saint-Aignan Cedex, France |
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Abstract: | Polyurethane acrylate resins cured by two different ways, a thermal way and a photochemical way, are investigated by means of differential scanning calorimetry (DSC) and thermally stimulated depolarization currents (TSDC). Even if both curing methods lead to the same material from a chemical point of view, we show that important differences exist between the thermocured resin and the photocured resin in terms of molecular relaxation behaviour.This revised version was published online in November 2005 with corrections to the Cover Date. |
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Keywords: | DSC enthalpic relaxation polyurethane TSDC |
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