Structural and composition changes in superconducting ceramics locally irradiated by electrons |
| |
| Authors: | Yu Ya Tomashpol’skii N V Sadovskaya C Diaz-Guerra J Piqueras C Opagiste |
| |
| Institution: | (1) L. Ya. Karpov Physical Chemistry Scientific-Research Institute, 103064 Moscow, Russia;(2) Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain;(3) Université de Savoie, B.P.240, 9 Rue de l’Arc-en-Ciel, F-74942 Annecy-le-Vieux, Cedex, France |
| |
| Abstract: | The structural changes and the cation and anion compositions of the surface of superconducting YBa2Cu3O7−x
and Tl2Ba2CuO6+x
ceramics after local irradiation for several seconds by an electron probe with an accelerating voltage of 25 kV and a current
exceeding 10−7 A are investigated by secondary-electron emission and by cathodoluminescence and x-ray microanalysis in a scanning electron
microscope. Morphologically altered regions are detected in the irradiation epicenter, where the structure, chemical composition,
and phase composition of the original compound are completely lost. In the intermediate zone between the epicenter and the
periphery a distribution of the secondary emission yield is observed with a complex character that differs for the yttrium
and thallium ceramics, and anomalies appear in the cathodoluminescence spectra. The experimental data are interpreted on the
basis of ideas of oxygen losses under the direct influence of the electron probe and related electronic processes in superconductors.
Fiz. Tverd. Tela (St. Petersburg) 39, 452–456 (March 1997) |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
