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| 混合配体配合物钯(Ⅱ)-联喹啉-苯乙基丙二酸根与DNA作用研究 | |
| 引用本文： | 高恩君,赵淑敏,刘祁涛. 混合配体配合物钯(Ⅱ)-联喹啉-苯乙基丙二酸根与DNA作用研究[J]. 无机化学学报, 2004, 20(2): 191-194 |
| 作者姓名： | 高恩君 赵淑敏 刘祁涛 |
| 作者单位： | 1. 沈阳化工学院配位化学研究室,沈阳,110142;东北师范大学化学学院,长春,130024 2. 沈阳化工学院配位化学研究室,沈阳,110142 3. 辽宁大学化学科学与工程学院,沈阳,110036;东北师范大学化学学院,长春,130024 |
| 基金项目： | 辽宁省自然科学基金资助项目(No.20022018)，沈阳化工学院拔尖人才基金资助项目。 |
| 摘 要： | The mixed ligand complex [Pd(biqu)(pmal)]·H2O (where biqu is 2,2′-biquinoline, pmal is phenethylmalonate) has been synthesized and its interaction with sperm DNA was determined by fluorescent spectra、 UV-Vis spectra and CD-spectra. The binding constant (Kb) of the complex and sperm DNA is 1.26×104 and its interaction with pBR322 plasmid DNA was also determined by gel electrophoresis. The results show that the complex interact with DNA mainly by intercalative mode. |
| 关 键 词： | 钯(Ⅱ) 联喹啉 苯乙基丙二酸 配合物 DNA |
| 修稿时间： | 2003-06-18 |
Study on the Interaction of Mixed Ligand Complex Palladium(Ⅱ)-biquinoline-phenethylmalonate with DNA |
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| GAO En-Jun,ZHAO Shu-Min and LIU Qi-Tao. Study on the Interaction of Mixed Ligand Complex Palladium(Ⅱ)-biquinoline-phenethylmalonate with DNA[J]. Chinese Journal of Inorganic Chemistry, 2004, 20(2): 191-194 | |
| Authors: | GAO En-Jun ZHAO Shu-Min LIU Qi-Tao |
| Affiliation: | Coordination Chemistry Section, Shenyang Institute of Chemical Technology, Shenyang 110142;Chemistry Department ,Northeast Normal University, Changchun 130024,Coordination Chemistry Section, Shenyang Institute of Chemical Technology, Shenyang 110142 and Chemical Department, Liaoning University, Shenyang 110036;Chemistry Department ,Northeast Normal University, Changchun 130024 |
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