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Molecular and crystal structure of the sequiterpene lactone austricin
Authors:K M Turdybekov  S M Adekenov  S V Lindeman  Yu T Struchkov
Abstract:An x-ray structural study has been made of the sesquiterpene lactone austricin: diffractometer, MoKα radiation, 1147 reflections, direct method, R=0.045. The spatial structure of the molecule has been determined. The conformation of the pentane carbocycle is 1α-envelope, of the heptane ring 1,10β, 7α-chair, and of the lactone ring 7α-envelope. The lactone ring is trans-linked with the guaiane skeleton. Institute of Organic Synthesis and Coal Chemistry, Kazakh SSR Academy of Sciences, Karaganda. A. N. Nesmeyanov Institute of Heteroorganic Compounds, USSR Academy of Sciences, Moscow. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 788–791, November–December, 1989.
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