Abstract: | An x-ray structural study has been made of the sesquiterpene lactone austricin: diffractometer, MoKα radiation, 1147 reflections, direct method, R=0.045. The spatial structure of the molecule has been determined. The conformation
of the pentane carbocycle is 1α-envelope, of the heptane ring 1,10β, 7α-chair, and of the lactone ring 7α-envelope. The lactone
ring is trans-linked with the guaiane skeleton.
Institute of Organic Synthesis and Coal Chemistry, Kazakh SSR Academy of Sciences, Karaganda. A. N. Nesmeyanov Institute of
Heteroorganic Compounds, USSR Academy of Sciences, Moscow. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 788–791,
November–December, 1989. |