Catalytic [2+1] cycloaddition of diazo compounds to [60]fullerene |
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Authors: | Tuktarov A. R. Akhmetov A. R. Sabirov D. Sh. Khalilov L. M. Ibragimov A. G. Dzhemilev U. M. |
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Affiliation: | (1) Department of Studies and Research in Industrial Chemistry, School of Chemical Sciences, Kuvempu University, Shankaraghatta, Karnataka, 577 451, India; |
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Abstract: | A catalytic method for the efficient synthesis of 5,6-open and 6,6-closed (2π+1π) fullerene adducts by [2+1] cycloaddition of ethyl 2-alkyl(hetaryl)-2-diazoacetates to [60]fullerene in the presence of a three-component catalyst Pd(acac)2—PPh3—Et3Al have been developed. |
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