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Catalytic [2+1] cycloaddition of diazo compounds to [60]fullerene
Authors:Tuktarov  A. R.  Akhmetov  A. R.  Sabirov  D. Sh.  Khalilov  L. M.  Ibragimov  A. G.  Dzhemilev  U. M.
Affiliation:(1) Department of Studies and Research in Industrial Chemistry, School of Chemical Sciences, Kuvempu University, Shankaraghatta, Karnataka, 577 451, India;
Abstract:A catalytic method for the efficient synthesis of 5,6-open and 6,6-closed (2π+1π) fullerene adducts by [2+1] cycloaddition of ethyl 2-alkyl(hetaryl)-2-diazoacetates to [60]fullerene in the presence of a three-component catalyst Pd(acac)2—PPh3—Et3Al have been developed.
Keywords:
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