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Stabilization of ammonium dinitramide in the liquid phase
Authors:Andreev  A. B.  Anikin  O. V.  Ivanov  A. P.  Krylov  V. K.  Pak  Z. P.
Affiliation:(1) Double Technology Federal Center "Soyuz,", 6 ul. Sovetskaya, 140056 Dzerzhinskii, Moscow Region, Russian Federation;(2) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation
Abstract:The kinetics of accumulation of the main products of thermal decomposition of ammonium dinitramide in the melt was investigated. The isotope composition of nitrogen-containing gases evolved by the decomposition of 15NH4N(NO2)2 and NH415N(NO2)2 was found. Easily oxidized salts, amines, amides, iodides, and other compounds soluble in the melt interfere with the liquid-phase decomposition of ammonium dinitramide.
Keywords:ammonium dinitramide  thermal decomposition  kinetics  stabilization  isotope composition
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