Combining coordination and supramolecular chemistry for the formation of uranyl-organic hybrid materials |
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Authors: | Deifel Nicholas P Cahill Christopher L |
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Institution: | Department of Chemistry, The George Washington University, 725 21st Street NW, Washington, DC 20052, USA. |
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Abstract: | Three hybrid compounds have been synthesized through hydrothermal reactions of UO(2)(NO(3))(2)·6H(2)O with 4-halobenzoic acid (X = Cl, Br, I). The formation of these compounds utilizes a composite synthesis methodology that explicitly employs aspects of both coordination chemistry and supramolecular chemistry (namely halogen···halogen interactions). |
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