Bis-boranes in the frustrated Lewis pair activation of carbon dioxide |
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| Authors: | Zhao Xiaoxi Stephan Douglas W |
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| Institution: | Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, Canada, M5S 3H6. |
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| Abstract: | Using a frustrated Lewis pair approach, the 1,1-bis-(C(6)F(5))(2)BOB(C(6)F(5))(2) is shown to bind CO(2) in a monodentate fashion, while the bis-boranes (X(2)B)(2)C=CMe(2) (X = Cl, C(6)F(5)) give bidentate chelation of CO(2) affording unique heterocycles. |
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