Analysis of polarizabilities of alkali halides using Narayan-Ramaseshan repulsive potential |
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Authors: | GG Agrawal HP Sharma Jai Shanker |
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Institution: | Department of Physics, Agra College, Agra-282002, India |
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Abstract: | The repulsive potential in ionic crystals recently proposed by Narayan and Ramaseshan (NR) can be expressed as the sum of the contributions from the individual ions. In the present paper we show that using this repulsive potential it is possible to divide the polarizability arising from the relative displacement of ions into its ionic constituents. NR have also derived the ionic radii in alkali halides which we have used to estimate the electronic polarizabilities of ions with the help of polarizability-radius cube relation. The electronic polarizabilities of alkali and halogen ions thus evaluated show a good agreement with those deduced from the experimental refraction data. |
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