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Surface-enhanced Raman study of organic sulfides adsorbed on silver |
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| Authors: | Tai Ha Joo Kwan Kim Myung Soo Kim |
| Affiliation: | Molecular Structure Group, Department of Chemistry, College of Natural Sciences, Seoul National University, Seoul 151 Korea |
| Abstract: | The surface-enhanced Raman scatterings of dimethyl sulfide, diethyl sulfide and dimethyl disulfide have been investigated in silver sol. The dimethyl disulfide molecule decomposes on silver to the corresponding mercaptide implying facile cleavage of its S---S bond. The C---S bond in dialkyl monosulfide appears not to cleave on silver. For diethyl sulfide, the C2 conformation seems to be favorable on silver than other conformations. |
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