| 合成硅氧醚的新方法：Silyltriflimides与醇或与醚反应 |
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| 引用本文： | 唐子龙. 合成硅氧醚的新方法：Silyltriflimides与醇或与醚反应[J]. 中国化学, 2008, 26(3): 525-530. DOI: 10.1002/cjoc.200890099 |
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| 作者姓名： | 唐子龙 |
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| 作者单位： | 湖南科技大学化学化工学院，分子构效关系湖南省高校重点实验室，湖南湘潭，411201 Department of Chemistry, University of Louvain, 1 Place de Pasteur, B-1348 Louvain-la-Neuve, Belgium |
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| 摘 要： | 首次利用silyltriflimides［双－（三氟甲磺酰）－亚胺基硅烷］与醇或醚反应合成了一系列非环链状或环状的硅氧醚，反应产率较好。其中反应物silyl triflimides很容易由相应的苯基硅烷或丙烯基硅烷与HNTf2通过质子脱硅化反应得到。合成的新化合物的结构用1H NMR, 13C NMR, MS, IR 和HRMS等进行了表征.
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| 关 键 词： | Silyltriflimide；硅氧醚；合成 |
| 收稿时间： | 2007-06-18 |
| 修稿时间： | 2007-10-09 |
A New Route to Preparations of Silyl Ethers by Reactions of Silyl Triflimides with Alcohol or Ether |
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| Zi‐Long TANG. A New Route to Preparations of Silyl Ethers by Reactions of Silyl Triflimides with Alcohol or Ether[J]. Chinese Journal of Chemistry, 2008, 26(3): 525-530. DOI: 10.1002/cjoc.200890099 |
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| Authors: | Zi‐Long TANG |
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| Affiliation: | 1. School of Chemistry and Chemical Engineering, Hunan Provincial University Key Laboratory of QSAR/QSPR, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China;2. Department of Chemistry, University of Louvain, 1 Place de Pasteur, B‐1348 Louvain‐la‐Neuve, Belgium |
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| Abstract: | A few of acyclic and cyclic silyl ethers were firstly synthesized in good yields by reactions of silyl triflimides with alcohol or ether. The corresponding silyl triflimides were easily produced by protodesilylation of phenyl or allyl silanes with HNTf2. All new compounds were characterized by 1H NMR, 13C NMR, MS, IR and HRMS. |
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| Keywords: | silyl triflimide silyl ether synthesis |
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