典型锕系超分子组装体的构筑原理及研究进展

锕系超分子化学是锕系元素化学的重要研究领域,可以为乏燃料后处理的配位化学基础研究提供重要信息,并为探索锕系功能材料在发光、传感、催化和分离等方面的功能应用提供关键材料体系。本文介绍了基于锕系金属离子的金属-有机超分子组装体这一新兴领域的最新研究进展。从锕系超分子组装体的构筑原理出发并结合笔者自身研究情况,对基于主客体准轮烷配体的锕系-轮烷配位聚合物、具有闭合结构的锕系配位组装体和基于超分子相互作用的锕系超分子聚合物这三类典型的锕系超分子组装体的研究进展进行了梳理和总结阐述。期望为未来新型锕系超分子组装体的设计合成提供参考,促进相关领域的进步和发展。

Construction Principles and Research Progress of Typical Actinide Supramolecular Assemblies

Actinide supermolecular chemistry is one of the recently emerging research areas of actinide chemistry, which can provide important information for the basic research of coordination chemistry of spent fuel reprocessing, and also explore the function and potential application of actinide functional materials in the fields of luminescence, catalysis, separation et al. This review will introduce recent progresses of actinide-based supramolecular assemblies. Starting from the construction principle of actinide-based supramolecular assemblies, and in combination with the author"s own research situation, the research progress of three typical kinds of actinide supramolecular assemblies including actinide-rotaxane complexes based on host-guest rotaxane ligands, actinide coordination complexes with closed structures and actinide supramolecular polymers based on supramolecular interactions is systematically reviewed and summarized. This review will provide a reference for the design and synthesis of new actinide-based supramolecular assemblies in the future and promote the progress and development of related fields of actinide chemistry and mateirals.