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Recent progress in transition metal catalyzed cross coupling of nitroarenes
Authors:Lifen Peng  Zhifang Hu  Zilong Tang  Yinchun Jiao  Xinhua Xu
Institution:a Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of Ministry of Education, Hunan; Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine Polymers, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China; b State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
Abstract:In this review, the recent development in transition metal catalyzed cross coupling of nitroarenes was highlighted. Firstly, development of transition metal catalyzed cross coupling was simply introduced. After presenting the advantages of nitroarenes, transition metal catalyzed cross coupling using nitroarenes as electrophilic coupling partners was classified and introduced in detail. Based on different chemical bonds such as C–O, C–S, C–C and C–N bonds constructed, different kinds cross coupling of nitroarenes would be highlighted and the plausible reaction mechanism would be presented if available.
Keywords:Transition metal  Catalysis  Nitroarenes  Cross coupling  Chemical bonds  
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