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Preparation and photochromic properties of pyrazolones/polyvinyl alcohol composite films
Authors:Ji-Xi Guo  Ming-Xi Guo  Dian-Zeng Jia  Yin-Hua Li
Institution:Key Laboratory of Energy Materials Chemistry, Ministry of Education;Key Laboratory of Advanced Functional Materials, Autonomous Region;Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, China
Abstract:Novel photochromic composite films have been successfully fabricated by dispersing pyrazolone derivative:1,3-Diphenyl-4-(3-chlorobenzal)-5-hydroxypyrazole 4-phenylsemicarbazone (1a) into hydrosol of polyvinyl alcohol (PVA). The microstructure, photochromic behaviors and thermal bleaching properties were investigated by Raman spectroscopy, X-ray powder diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and ultraviolet-visible absorption spectroscopy (UV-vis). The results showed that 1a was not only blended but also well dispersed in the PVA polymer films with a suitable content of chromophore. Upon UV light irradiation, the composite films gradually changed from colorless to yellow and recovered fully to the initial state upon thermal bleaching. The time constants of photochromic reactions were almost the same as those of 1a observed in their crystalline state, indicating that the photochromic phenomenon is barely disturbed by the polymer matrix.
Keywords:Pyrazolone  Polyvinyl alcohol  Composite film  Photochromism  Information storage  
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