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Cesium lead halide perovskite nanocrystals for ultraviolet and blue light blocking
Authors:Guihua Huang  Yipeng Huang  Wei Xu  Qiuhong Yao  Xiaofang Liu  Caifeng Ding  Xi Chen
Institution:1. Institute of Analytical Technology and Smart Instruments, College of Environment and Public Health, Xiamen Huaxia University, Xiamen 361024, China;2. State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen 361005, China;3. Department of Anesthesiology, Xiamen Maternal and Children Hospital, Xiamen 361003, China;4. Key Laboratory of Sensor Analysis of Tumor Marker, Ministry of Education, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
Abstract:Using cesium lead halide perovskite nanocrystals, CsPb(Cl/Br)3, as a light absorber, we report a highly effective UV and blue light blocking film. The CsPb(Cl/Br)3 nanocrystals are well dispersed in the ethyl cellulose (EC) matrix to compose a UV and blue light shielding film, and the absorption edge of the film is tunable by adjusting Cl to Br ratio using anion exchange. The CsPbCl2Br-EC film exhibits a transmittance of 5% at 459 nm, 90% at 478 nm and 95% in the range of 500-800 nm, which makes it excellent for UV and blue light shielding. In addition, the as-prepared EC-CsPb(Cl/Br)3 film shows excellent photostability under UV irradiation. Results demonstrate that this EC-CsPb(Cl/Br)3 based materials with sharp absorbance edges, tunable blocking wavelength, and high photostability can be useful for the applications in UV and blue light blocking and optical filters
Keywords:Perovskite nanocrystals  UV blocking  Blue light blocking  Cesium lead halide nanocrystals  Tunable adsorption edge  
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