Thermochemistry of heteroatomic compounds |
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| Authors: | V V Ovchinnikov L I Lapteva M G Kireev |
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| Institution: | (1) Kazan State Academy of Construction and Architecture, 1 ul. Zelenaya, 420043 Kazan, Russian Federation |
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| Abstract: | The enthalpies of combustion ( H
comb) of 13 primary, secondary, and tertiary alkylphoshines in the condensed state were calculated using the equation H
comb = –860.7 – 107.0N, where N is the number of valent (bond-forming) electrons. This equation can be used for the calculation of enthalpies of combustion and formation of phosphoric acid esters.Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1693–1694, August, 2004. |
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| Keywords: | phosphines phosphites enthalpy of combustion enthalpy of formation |
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