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添加助熔剂后朱集西煤灰熔融特性规律研究
引用本文:王大川,梁钦锋,龚欣,刘海峰,刘霞.添加助熔剂后朱集西煤灰熔融特性规律研究[J].燃料化学学报,2015,43(2):153-159.
作者姓名:王大川  梁钦锋  龚欣  刘海峰  刘霞
作者单位:Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, Shanghai Engineering Research Center of Coal Gasification, East China University of Science & Technology, Shanghai 200237, China
基金项目:国家高技术研究发展计划(863计划, 2013AA051103); 国家自然科学基金(21106046)。
摘    要:以高灰熔点朱集西洗煤为对象,研究了助熔剂CaCO3、Fe2O3、CaCO3/Fe2O3复合助熔剂以及CaMg(CO3)2对其煤灰熔融特性的影响。结果表明,各助熔剂均可降低煤灰熔融温度,但助熔效果与助熔剂种类和添加量有关,采用CaCO3/Fe2O3复合助熔剂以及CaMg(CO3)2在添加量较小时,助熔效果明显;利用FactSage热力学软件,分析了添加助熔剂对煤灰中矿物高温熔融行为的影响,为进一步掌握助熔剂的助熔机理提供理论帮助。

关 键 词:煤灰熔融温度  助熔剂  矿物转变  
收稿时间:2014-08-26

Fusion properties of Zhujixi washed coal ash adding fluxes
WANG Da-chuan,LIANG Qin-feng,GONG Xin,LIU Hai-feng,LIU Xia.Fusion properties of Zhujixi washed coal ash adding fluxes[J].Journal of Fuel Chemistry and Technology,2015,43(2):153-159.
Authors:WANG Da-chuan  LIANG Qin-feng  GONG Xin  LIU Hai-feng  LIU Xia
Institution:Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, Shanghai Engineering Research Center of Coal Gasification, East China University of Science & Technology, Shanghai 200237, China
Abstract:The Zhujixi washed coal has high ash fusion temperature which were studied by adding fluxes calcium carbonate, ferric oxide, complex flux and dolomite. The results indicate that all fluxes can reduce the ash fusion temperature which is varied depending on different species and mass of fluxes addition. Ash fusion temperature can remarkably be reduced by adding small amount of complex flux or dolomite. By using thermodynamic FactSage software, the mineral compositions at high temperature of coal ash with flux were studied. This will be helpful to explain how the fluxes can improve the fusion properties.
Keywords:ash fusion temperature  fluxes  mineral transformation
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