Structures of bis(cyclopentadienyl) binuclear titanium complexes |
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| Authors: | Sh. G. Mkoyan Z. G. Aliev I. F. Urazovskii L. O. Atovmyan I. E. Nifant'ev K. A. Butakov |
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| Affiliation: | (1) Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation;(2) Department of Chemistry, M. V Lomonosov Moscow State University, Vorab 'evy Gory, 119899 Moscow, Russian Federation |
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| Abstract: | The (C5H4-XMe2-C5H4) · (TiCl3)2 binuclear complexes, where X = Si (1) or C (2), have been studied by X-ray structural analysis. In both structures, the coordination polyhedra about the Ti atoms are distorted tetrahedra formed by three CI atoms and one Cp ring. The conformations of molecules1 and2 and the possibility of the occurrence of secondary Ti-Cp...Cl-Ti interaction are discussedTranslated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2269–2271, September. 1996. |
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| Keywords: | titanium cyclopentadienyl binuclear complex conformation molecular and crystal structure |
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