| 几种取代螺吲哚啉萘并噁嗪的合成 |
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| 引用本文： | 李仲杰,谭永生,马引民,王晓信.几种取代螺吲哚啉萘并噁嗪的合成[J].应用化学,1992,0(4):83-86. |
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| 作者姓名： | 李仲杰 谭永生 马引民 王晓信 |
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| 作者单位： | 西北大学化学系, 西安 710069 |
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| 基金项目： | 国家自然科学基金，陕西省科委基金 |
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| 摘 要： | 螺吲哚啉-2,3'-3H]萘并2,1-b]1,4]噁嗪(简称螺噁嗪)是一类耐光疲劳性能优于螺吡喃的光致变色物1]。Fox以及Ono先期合成了这类化合物2],最近Pottier等考察了取代基对性能的影响3,4]。但所涉及的取代基(CH3、CH3O、Cl、NO2)多在母体结构中吲哚环的5( 6)位,且N-烷基碳链较短,蔡环上有取代基的情形较少见5]。
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| 关 键 词： | 螺噁嗪 光致变色 |
| 收稿时间： | 1991-09-26 |
| 修稿时间： | 1991-11-20 |
SYNTHESIS OF SOME SUBSTITUTED INDOLINOSPIRONAPHTHOXAZINES |
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| Li Zhongjie,Tan Yongsheng,Ma Yinmin,Wang Xiaoxin.SYNTHESIS OF SOME SUBSTITUTED INDOLINOSPIRONAPHTHOXAZINES[J].Chinese Journal of Applied Chemistry,1992,0(4):83-86. |
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| Authors: | Li Zhongjie Tan Yongsheng Ma Yinmin Wang Xiaoxin |
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| Institution: | Department of Chemistry, Northwest University, Xi'an 710069 |
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| Abstract: | Some N-alkyl, 5'-methoxycarbonyl and 8'-bromo derivatives of spiroindoline-2,3'-3H-naphth2,1-b]1,4]oxazines] were synthesized by reacting corresponding substituted nitrosoonaphthols with Fischer base in anhydrous ethanol. Their structures were identified by elemental analysis and spectral methods. The photochromic behavior of the spirooxazines in toluene solution and polymer film were also examined. |
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| Keywords: | spirooxazine photochromism |
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