Mesure des chaleurs de Mélange de duex liquides,sans programmation des débits,avec le microcalorimètre picker à écoulement |
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Authors: | Americo Inglese Jean-Pierre E Grolier |
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Institution: | Centre de Recherches de Microcalorimétrie et de Thermochimie du C.N.R.S., Section de Themodynamique des Alliages et des Mélanges Moléculaires, 26, rue du 141° R.I.A., 13003 Marseille France |
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Abstract: | A method is proposed for using the Picker microcalorimeter without programmation of the flow rates of the reactant liquids. From the measurements of the three systems (carbon tetrachloride+benzene, +n-heptane and +cyclopentane) it is shown that the excess enthalphy curves obtained point by point are better defined than those obtained directly in the scanning mode, especially in the dilute regions. |
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