A pyrolysis/gas chromatography—mass spectrometry and thermogravimetry/differential thermal analysis study of bis(diethyldithiocarbamato)diphenyl tin (IV) |
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| Authors: | G.K. Bratspies J.F. Smith J.O. Hill R.J. Magee |
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| Affiliation: | Departments of Physical and Inorganic and Analytical Chemistry, La Trobe University, Bundoora, Victoria, 3083 Australia |
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| Abstract: | The P/GC—MS and TG/DTA analysis, in an inert atmosphere, of bis(diethyldithiocarbamato)diphenyl tin (IV) indicates that the thermal decomposition proceeds in two consecutive stages. Loss of the dithiocarbamate ligands and the phenyl groups occurs within the temperature range of 210–380°C leaving tin (II) sulphide as residue. The stability of the phenyl radical as a reactive intermediate, together with the unidentate bonding of the dithiocarbamate ligand, dramatically influence the major mode of thermal decomposition. |
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| Keywords: | To whom correspondence should be addressed. |
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