Department of General and Inorganic Chemistry B. University of Ghent, K.L. Ledeganckstraat 35, B-9000 Ghent Belgium
Abstract:
The enthalpies of the reactions in 0.5 M KNO3 at 25°C between the hydrogen and silver(I) ions and a number of sulfur-containing amines of the general formula R'-S-(CH2)NR2 where and n=2,3, have been determined by means of direct calorimetric titrations. By the use of the ΔG values reported elsewhere, the corresponding ΔS values have been calculated. the complex formation in acid, neutral and alkaline medium is discussed.
