A new Co(II) complex with N,O-donor Schiff base: Synthesis, structure and characterization |
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| Authors: | L. Xu Yu. V. Mironov X. Qi S.-J. Kim |
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| Affiliation: | (1) Information College of Science and Technology, Nanjing Forestry University, Nanjing, 210037, P. R. China;(2) Department of Chemistry and Division of Nano Science, Ewha Womans University, Seoul, 120-750 Seoul, Korea;(3) A. V. Nikolaev Institute of Inorganic Chemistry, Novosibirsk |
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| Abstract: | A new Co(II) complex with tridentate Schiff base ligand with a N,N,O donor set has been synthesized and characterized by single X-ray technique and spectroscopic techniques. The thermochemical properties have been studied. X-ray structure analysis of the title compound Co(II)L2 [HL = 2-methyl-6-(2′-hydroxybenzylideneamino) pyridine] shows that the polyhedron around Co(II) is a distorted tetrahedron, and the self-assembly via intermolecular π-π interactions leads to a three-dimensional network. Crystal data for the title complex C26H22CoN4O2: Monoclinic, space group Ia, a = 11.741(7) Å, b = 8.149(5) Å, c = 22.764(16) Å, β = 98.530(12)°, V = 2154(2) Å3, Z = 4. |
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| Keywords: | Schiff base ligand Co(II) complex crystal structure weight loss |
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