A new organometallic heteropolytungstate related to [Sb2W22O74(OH)2](12-): synthesis and structural characterisation of the bis-{Ru(p-cymene)}(2+)-containing anion [Sb2W20O70{Ru(p-cymene)}2](10-) |
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| Authors: | Laurencin Danielle Villanneau Richard Herson Patrick Thouvenot René Jeannin Yves Proust Anna |
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| Institution: | Laboratoire de Chimie Inorganique et Matériaux Moléculaires, UMR 7071, Université Pierre et Marie Curie, 4 Place Jussieu, Case courrier 42, 75252, Paris cedex 05, France. |
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| Abstract: | The easy synthesis of Sb2W20O70{Ru(p-cymene)}2](10-) by the reaction between the organometallic precursor Ru(p-cymene)Cl2]2 and Sb2W20O70]14-, formed in situ, confirms the importance of the organometallic route to well defined ruthenium(+II)-substituted heteropolytungstates. |
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