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多环类苝四甲酸二酐插入层对ZnO纳米棒和聚合物复合太阳电池性能的影响
引用本文:闫悦,赵谡玲,徐征,龚伟,王大伟. 多环类苝四甲酸二酐插入层对ZnO纳米棒和聚合物复合太阳电池性能的影响[J]. 物理学报, 2011, 60(8): 88803-088803. DOI: 10.7498/aps.60.088803
作者姓名:闫悦  赵谡玲  徐征  龚伟  王大伟
作者单位:北京交通大学光电子技术研究所,发光与光信息技术教育部重点实验室,北京 100044
基金项目:国家自然科学基金(批准号:60978060,10974013,10774013)和北京市自然科学基金(批准号:1102028)资助的课题.
摘    要:以ZnO纳米棒和聚[2-甲氧基-5-(2-乙基-己氧基)-1,4-苯撑乙烯撑](MEH-PPV)的复合体系作为光敏层制备了太阳电池.为了增大电池的光吸收,在ZnO纳米棒与MEH-PPV之间插入了有机n型小分子多环类苝四甲酸二酐(PTCDA),制备了不同厚度的PTCDA、结构为ITO/ZnO纳米棒/PTCDA/MEH-PPV/Au的太阳电池.实验发现,插入PTCDA后,电池在可见光区的吸收增强,光生激子数量增大,光电流密度增大.当蒸镀的PTCDA厚度为40 nm时,薄膜的粗糙度适中,表面形貌较为平滑,器件性关键词:有机太阳电池ZnO纳米棒聚合物

关 键 词:有机太阳电池  ZnO纳米棒  聚合物
收稿时间:2010-09-07

Effect of 3,4,9,10-perylenetetracarboxylic dianhydride on the performance of ZnO nanorods/polymer hybrid solar cell
Yan Yue,Zhao Su-Ling,Xu Zheng,Gong Wei and Wang Da-Wei. Effect of 3,4,9,10-perylenetetracarboxylic dianhydride on the performance of ZnO nanorods/polymer hybrid solar cell[J]. Acta Physica Sinica, 2011, 60(8): 88803-088803. DOI: 10.7498/aps.60.088803
Authors:Yan Yue  Zhao Su-Ling  Xu Zheng  Gong Wei  Wang Da-Wei
Affiliation:Key Laboratory of Luminescence and Optical Information of Ministry of Education, Institute of Optoelectronics Technology, Beijing Jiaotong University, Beijing 100044, China;Key Laboratory of Luminescence and Optical Information of Ministry of Education, Institute of Optoelectronics Technology, Beijing Jiaotong University, Beijing 100044, China;Key Laboratory of Luminescence and Optical Information of Ministry of Education, Institute of Optoelectronics Technology, Beijing Jiaotong University, Beijing 100044, China;Key Laboratory of Luminescence and Optical Information of Ministry of Education, Institute of Optoelectronics Technology, Beijing Jiaotong University, Beijing 100044, China;Key Laboratory of Luminescence and Optical Information of Ministry of Education, Institute of Optoelectronics Technology, Beijing Jiaotong University, Beijing 100044, China
Abstract:ZnO nanoroods/poly (MEH-PPV) hybrid solar cells are fabricated and their properties are discussed. In order to improve the absorption of sunlight, a layer of 3,4,9,10-perylenetetracarboxylic dianhydride(PTCDA) is inserted between ZnO nanorods and MEH-PPV, and cells with the structure ITO/ZnO nanorods/PTCDA/MEH-PPV/Au are prepared with different thickness values of PTCDA. After introducing PTCDA, the devices show a strong and broad absorption in visible region, which increases the number of photo-induced excitons and thus results in an enlarged photocurrent. When the thickness of PTCDA is 40 nm, we can observe the smooth morphology of thin layer surface, and achieve the best performance of the device.
Keywords:organic solar cell  ZnO nanorods  polymer
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