Functionalized nanodiamonds part 3: thiolation of tertiary/bridgehead alcohols |
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| Authors: | Tkachenko Boryslav A Fokina Natalie A Chernish Lesya V Dahl Jeremy E P Liu Shenggao Carlson Robert M K Fokin Andrey A Schreiner Peter R |
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| Institution: | Institut für Organische Chemie, Justus-Liebig University, Heinrich-Buff-Ring 58, D-35392 Giessen, Germany. |
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| Abstract: | reaction: see text] Treatment of acyclic as well as polycyclic tertiary mono- and dihydroxy hydrocarbon derivatives with thiourea in the presence of hydrobromic and acetic acid represents a convenient one-step route to the respective tertiary thiols and dithiols. This procedure was used for the preparation of diamondoid thiols of diamantane, triamantane, 121]tetramantane, and others that are prospective nanoelectronic materials. |
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