The Synthesis,Spectral, and Electrochemical Characterization of Novel Alkoxybenzoquinone Derivatives |
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Authors: | Cemil Ibis Sibel Sahinler Ayla Kadriye Cakan |
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Institution: | Department of Chemistry, Faculty of Engineering, Istanbul University, Istanbul, Turkey |
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Abstract: | The novel monosubstituted benzoquinone compounds 3e , 3g , 3h ; 2,5‐O‐ substituted benzoquinone compounds 4a , 4b , 4c , 4d , 4e 4g and known compound 4h and 2,6‐O‐ substituted benzoquinone compounds 5e , 5f , 5g , 5h were obtained by the reaction of p‐chloranil ( 1 ) and related alcohol compounds in potassium carbonate (K2CO3) solution of acetonitrile or chloroform with Et3N. The novel cyclic compounds 7 , 8 and 10 , 11 were obtained from the reaction of p‐chloranil ( 1 ) and diols in potassium carbonate (K2CO3) solution of acetonitrile at room temperature. The structures of novel compounds were characterized by using micro analysis, FT‐IR, 1H‐NMR, 13C‐NMR, MS and cyclic voltammetry. |
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