Cationic palladium(II)-catalyzed highly enantioselective [3+2] annulation of 2-acylarylboronic acids with substituted alkynes |
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Authors: | Yang Miao Zhang Xumu Lu Xiyan |
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Institution: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 354 Fenglin Road, Shanghai 200032, China. |
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Abstract: | A cationic palladium(II)-catalyzed enantioselective tandem 3+2] annulation of 2-acylarylboronic acids with substituted alkynes to yield optically active 1-indenols was developed in high yields and excellent enantioselectivities. |
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