Sonocatalytic oxidation of olefins catalyzed by heteropolyanion–montmorillonite nanocomposite |
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Authors: | Hossein Salavati Shahram Tangestaninejad Majid Moghadam Valiollah Mirkhani Iraj Mohammadpoor-Baltork |
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Affiliation: | aDepartment of Chemistry, Payame Noor University (PNU), Isfahan 81395-671, Iran;bDepartment of Chemistry, Catalysis Division, University of Isfahan, Isfahan 81746-73441, Iran |
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Abstract: | A Keggin-type heteropolyanion compound (HPO) was doped within the montmorillonite (MMT) structure by impregnation method. The synthesized catalyst was characterized by FT-IR, XRD, UV–vis, CV, SEM and elemental analysis. Based on chemical adsorption between HPO, and hydroxyl surface groups, HPOs nanoparticles were successfully located on the MMT. Moreover, the obtained nanocomposite was found as an efficient catalyst for oxidation of hydrocarbons under reflux and ultrasonic irradiation conditions. |
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Keywords: | Heteropolyanion Supported catalyst Montmorillonite Nanocomposite Epoxidation |
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