Diffusion in multiphase systems with nonstationary boundaries |
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Authors: | Petr Kubíček Libor Mrázek |
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Institution: | (1) Na čtvrti 14, 705 00 Ostrava 3, Czech Republic;(2) State Bureau of Nuclear Safety, Partyzánské nám. 7, 70157 Ostrava 1, Czech Republic |
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Abstract: | In this work the problem of diffusion in the definite diffusion field whose one boundary is fixed and the other — interphase
boundary — moves in time according to the parabolic law. The mathematical problem is solved exactly by means of thermal potentials
of a double layer. The solution of the diffusion equation in the proximity to the boundary was derived and the concentration
gradients on these boundaries were calculated. The numerical procedure of determining the diffusion characteristics from experimental
concentration gradients on the phase boundaries was presented. As the zero approximation the result of calculations according
to Wagner’s solution was used.
Theory.
Numerical calculations. |
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Keywords: | |
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