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| ELECTROCARBOXYLATION OF ORGANIC COMPOUNDS WITH CARBON DIOXIDE CATALYTZED BY METALLOPORPHYRINS(Ⅳ)——EFFECT OF VARIOUS FACTORS ON ELECTROCARBOXYLATION | |
| 摘 要： | The effects of various factors on the electrocarboxylation of organic compounds withcarbon dioxide catalyzed by metalloporphyrin are studied.The optimal potential of electrocar-boxylation is -1.6 V(vs.SCE).A weak protic solvent methanol can enhance catalytic activity.Tetrabutylammonium iodide is the best one of five electrolytes.The yields and current efficienciesof electrocarboxylation are increased slowly as the concentration of catalyst increases. |
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