| 环亮氨酸的合成 |
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| 引用本文： | 高仁孝,何永梁,沈宁. 环亮氨酸的合成[J]. 合成化学, 2009, 17(2) |
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| 作者姓名： | 高仁孝 何永梁 沈宁 |
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| 作者单位： | 西安瑞联近代电子材料有限公司,陕西,西安,710065;西安建筑科技大学,理学院,陕西,西安,710055;西安建筑科技大学,理学院,陕西,西安,710055;西安瑞联近代电子材料有限公司,陕西,西安,710065 |
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| 摘 要： | 以甘氨酸为起始原料,经酯化、酰胺化、脱水、成环及水解5步反应后,过阳离子交换柱合成了环亮氨酸,总收率52%,其结构经1H NMR和IR确证.
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| 关 键 词： | 甘氨酸 环亮氨酸 成环 合成 |
Synthesis of Cycloleucine |
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| GAO Ren-xiao,HE Yong-liang,SHEN Nin. Synthesis of Cycloleucine[J]. Chinese Journal of Synthetic Chemistry, 2009, 17(2) |
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| Authors: | GAO Ren-xiao HE Yong-liang SHEN Nin |
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| Affiliation: | 1.Xi'an Ruilian Modern Electronic Materials Co.Ltd;Xi'an 710065;China;2.School of science;Xi'an University of Architecture & Technology;Xi'an 710055;China |
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| Abstract: | Cycloleucine in total yield of 52% was synthesized from glycine by a five-step reaction of esterification,amidation,dehydration,cyclization and hydrolysis,and then treated with cationic ion-exchange resin.The structure was confirmed by 1H NMR and IR. |
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| Keywords: | glycine cycloleucine cyclization synthesis |
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