On the Existence and Stability of Spatially Structured Solutions of the Reaction-Diffusion Equations |
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Authors: | GRAHAM-EAGLE J G; GRAY B F; WAKE G C |
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Institution: |
Mathematics Department, Victoria University of Wellington New Zealand
Department of Physical Chemistry, University of Leeds Leeds LS2 9JT, U.K.
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Abstract: | The reaction-diffusion equations for the well-known Brusselatorchemical kinetic model are investigated when the model is madeconsistent with the principle of detailed balance. In contrastto the original model, the corrected one does not show solutionswith spatial structure i.e. solutions with multipleinternal maxima and multiple internal global minima in bothdependent variables. Sufficient conditions for stability ofthe solutions are given in terms of a Rayleigh quotient forgeneral boundary conditions for nonlinear reaction-diffusionequations in general. For the particular case of the Brusselatorit is shown that conditions for a change of stability are muchmore unlikely to be attained as a result of the restrictionsof detailed balancing. The detailed sufficiency condition forthe stability of any steady-state solution and for no branchingfrom the equilibrium branch solution depends onwhether the solution has global extrema inside the region, onits boundary, or both |
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