Synthesis and Characterization of a Reduced Molybdenum(V) Phosphate,(H3dien)2(H2dien)2[NaMo12O24(OH)6-(H2PO4)(HPO4)5(PO4)2]·nH2O (n = 10.92) |
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作者姓名: | CAO Xue-Gong LINBi-Zhou GENG Feng LI Xiao-Li XIAO Zi-Jing |
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作者单位: | College of Materials Science and Engineering,Huaqiao University, Quanzhou 362021, China |
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基金项目: | This work was supported by the Natural Science Foundation of Fujian Province (Nos. E0420001 and E0640006) and NCETFJ |
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摘 要: | A new reduced molybdenum(V) phosphate (H3dien)2(H2dien)2NaMo12O24 (OH)6 (HEPO4)(HPO4)5(PO4)2]·nH2O (n= 10.92, dien = diethylenetriamine) has been synthesized under hydrothermal conditions and characterized by elemental analyses, IR and X-ray diffraction. C16H96.84MO12N12NaO72.92P8 (Mr = 3046.73) crystallizes in the monoclinic system, space group P21/c with a = 13.3575(18), b = 21.907(3), c = 15.654(2)A, β= 110.22(2)°, V= 4298.4(10) A^3 Dc = 2.354 g/cm^3, Z = 2,μ(MoKcr) = 1.966 mm^-1, F(000) = 2990.4, the final R = 0.0357 and wR = 0.1086 for 8739 observed reflections with I 〉 2σ(I). It consists of sandwich-shaped cluster anions Na{Mo6P4}2]^10- held together into a three-dimensional supramolecular framework through intermolecular hydrogen-bonding contacts. A probe reaction of the oxidation of acetaldehyde with H2O2 showed that this compound has high catalytic activity in the reaction.
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关 键 词: | 磷酸钼 水热合成 晶体结构 催化作用 |
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