Crystal structure of tris-(dipivaloylmethanato) (ethylendiamine)yttrium(III) |
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Authors: | S. A. Mosyagina N. V. Kuratieva K. V. Zherikova |
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Affiliation: | 1.Novosibirsk National Research State University,Novosibirsk,Russia;2.Nikolaev Institute of Inorganic Chemistry, Siberian Branch,Russian Academy of Sciences,Novosibirsk,Russia |
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Abstract: | The structure of a mixed-ligand complex tris-(dipivaloylmethanato)(ethylendiamine)yttrium(III) [Y(en)(dpm)3] is studied at 150(2) K by single crystal XRD. The crystallographic data for C35H65N2O6Y are as follows: space group P21/c, a = 10.3771(3) Å, b = 26.3566(8) Å, c = 14.8412(4) Å, β = 100.385(2)°, V = 3992.6(2) Å3, Z = 4. The structure is molecular. The coordination environment of yttrium atoms is square antiprismatic; the Y–О distances are 2.2597(13)-2.3760(12) Å and Y–N distances are 2.5381(16) Å and 2.5499(17) Å. |
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