Hierarchical organization of a robust porphyrin cage self-assembled by hydrogen bonds |
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| Authors: | Singh Sunaina Aggarwal Amit Farley Christopher Hageman Brian A Batteas James D Drain Charles Michael |
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| Affiliation: | Department of Chemistry & Biochemistry, Hunter College of The City University of New York, 695 Park Avenue, New York, NY 10065, USA. |
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| Abstract: | Porphyrins appended with four rigid hydrogen bonding motifs on the meso positions were synthesized and self-assembled into a cofacial cage with four complementary bis(decyl)melamine units in dry solvents. The hydrocarbon chains on the melamine mediate the formation of nanofilms on surfaces as the solvent slowly evaporates. |
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