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X-ray photoelectron spectroscopy of some Co(II) dithiocarbamates |
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| Authors: | Giovanni Polzonetti Carlo Preti Giuseppe Tosi |
| Affiliation: | Department of Chemistry, University “La Sapienza”, P. le A. Moro, 5, 00185 Rome, Italy Department of Chemistry, University of Modena, Via G. Campi, 183, 41100 Modena, Italy |
| Abstract: | The X-ray photoelectron spectra of a series of Co(II) dithiocarbamate complexes have been studied. Data confirmed the substantial identity of the electronic structure of the chromophores throughout the series, and Co2P3/2 BE values of 780.1 eV are in good agreement with the expectation on the base of Feltham-Brant scale. Shake-up satellites associated with the Co2P3/2 photoelectron line have been investigated and compared with magnetic moments. |
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