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MELT BLENDS OF POLY (BUTYLEN TEREPHTHALATE) AND A THERMOTROPIC LIQUID CRYSTALLINE POLYMER
引用本文:何嘉松,卜文胜,张洪志,郑淑昀,许向青. MELT BLENDS OF POLY (BUTYLEN TEREPHTHALATE) AND A THERMOTROPIC LIQUID CRYSTALLINE POLYMER[J]. 高分子科学, 1994, 0(2): 106-113
作者姓名:何嘉松  卜文胜  张洪志  郑淑昀  许向青
作者单位:State Key Laboratory of Engineering Plastics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,State Key Laboratory of Engineering Plastics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,State Key Laboratory of Engineering Plastics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,State Key Laboratory of Engineering Plastics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,Beijing Research Institute of Chemical Industry,Mnistry of Chemical Industry,Beijing 100013
基金项目:Supported by the National Natural Science Foundation of China
摘    要:With the help of differential scanning calorimetry, cone-plate and capillary rheometry andscanning electron microscopy, a research has been conducted on rheological behavior,crystallization and morphology of poly (butylene terephthalate) (PBT) blends containing athermotropic LCP. The blend has zero entrance pressure loss, although the LCP has rather largeone. The viscosity curve of the blend lies between those of the LCP and PBT. The crystallizationof PBT is not affected by the presence of the LCP together with no indication oftransesterification between the two ingredients. LCP spheres and ellipsoids with the size of 0. 5--1. 5 μm disperse in PBT matrix uniformly, which is related to the viscosity ratio of the twocomponents.

收稿时间:1992-10-20

MELT BLENDS OF POLY (BUTYLEN TEREPHTHALATE) AND A THERMOTROPIC LIQUID CRYSTALLINE POLYMER*
HE Jiasong,BU Wensheng,ZHANG Hongzhi,ZHENG Suyun,XU Xiangqin. MELT BLENDS OF POLY (BUTYLEN TEREPHTHALATE) AND A THERMOTROPIC LIQUID CRYSTALLINE POLYMER*[J]. Chinese Journal of Polymer Science, 1994, 0(2): 106-113
Authors:HE Jiasong  BU Wensheng  ZHANG Hongzhi  ZHENG Suyun  XU Xiangqin
Affiliation:State Key Laboratory of Engineering Plastics; Institute of Chemistry; Chinese Academy of Sciences; Beijing; Beijing Research Institute of Chemical Industry; Mnistry of Chemical Industry
Abstract: With the help of differential scanning calorimetry, cone-plate and capillary rheometry andscanning electron microscopy, a research has been conducted on rheological behavior,crystallization and morphology of poly (butylene terephthalate) (PBT) blends containing athermotropic LCP. The blend has zero entrance pressure loss, although the LCP has rather largeone. The viscosity curve of the blend lies between those of the LCP and PBT. The crystallizationof PBT is not affected by the presence of the LCP together with no indication of transesterification between the two ingredients.LCP spheres and ellipsoids with the size of 0.5-1.5μm disperse in PBT matrix uniformly,which is related to the viscosity ratio of the two components.
Keywords:Polybutylene terephthalate (PBT)  Thermotropic liquid crystalline polymer  Melt Blend  
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