A novel transformation of a 1 : 1 : 1 racemic complex of 2,2'-dihydroxy-1,1'-binaphthyl, Me4N+ Cl- and MeOH into a conglomerate in the solid state by heating or contact with MeOH vapour |
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| Authors: | Yoshizawa Kazuhiro Toyota Shinji Toda Fumio |
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| Institution: | Department of Chemistry, Faculty of Science, Okayama University of Science, Ridai-cho 1-1, Okayama 700-0005, Japan. |
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| Abstract: | The title racemate-to-conglomerate transformation which occurs in the solid state on heating or contact with MeOH vapour has been studied by IR and DTA spectral measurements, microscopic observation, and by X-ray structural and X-ray powder diffraction analysis. |
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