Copper-catalyzed silylation of cyclopropenes using (trifluoromethyl)trimethylsilane |
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| Authors: | Fordyce Euan A F Wang Yi Luebbers Thomas Lam Hon Wai |
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| Affiliation: | School of Chemistry, University of Edinburgh, Joseph Black Building, The King's Buildings, West Mains Road, Edinburgh, UK. |
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| Abstract: | A variety of cyclopropenes undergo direct silylation using (trifluoromethyl)trimethylsilane in the presence of a copper-bisphosphine catalyst; under these conditions, cyclopropenes that might otherwise undergo ring-opening are silylated efficiently. |
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