A Luminescent Silver(I) Metal‐Organic Framework with New (4,6)‐Connected Topology Based on Mixed Tetrachloroterephthalate and 2,2′‐Bipyridine Ligands |
| |
| Authors: | Sheng‐Chun Chen Xiao‐Xiao Cai Zhi‐Hui Zhang Qi Yan Ming‐Yang He Feng Tian Jian Gao Qun Chen |
| |
| Affiliation: | 1. Key Laboratory of Fine Petrochemical Technology, Changzhou University, Changzhou 213164, P. R. China;2. School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, P. R. China |
| |
| Abstract: | A silver(I) coordination polymer with mixed 2,3,5,6‐tetrachloro‐1,4‐benzenedicarboxylate (BDC‐Cl4) and 2,2′‐bipyridine (2,2′‐bpy) ligands, [Ag2(BDC‐Cl4)(2,2′‐bpy)]n ( 1 ), was synthesized and structurally characterized. Compound 1 features a robust three‐dimensional (3D) network, exhibiting a new (4,6)‐connected net with the Schläfli symbol of (32 · 42 · 5 · 6)2(32 · 42 · 52 · 87 · 9 · 10). The photoluminescence properties of 1 were investigated in the solid state at room temperature. |
| |
| Keywords: | Coordination polymer Silver Crystal structure Topology Photoluminescence |
|
|
