A Luminescent Cage‐Like Complex Constructed by Bidentate Pyridine‐Containing Ligand and Silver Nitrate |
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| Authors: | Ying Liu Ying‐Hui Yu Yi‐Fu Liu Guang‐Feng Hou Xiao‐Dan Wang Bo Wen Jin‐Sheng Gao |
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| Affiliation: | 1. School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, P. R. China;2. School of Materials and Chemistry Engineering, Heilongjiang Institute of Technology, Harbin 150050, P. R. China;3. Engineering Research Center of Pesticide of Heilongjiang University, Heilongjiang University, Harbin 150050, P. R. China |
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| Abstract: | The cage‐like complex, Ag4L4(NO3)4 ( 1 ) [L = 1, 4‐bis(pyridine‐2‐ylmethoxy)benzene] was synthesized by the reaction of the flexible bidentate ligand and silver nitrate. It was characterized by elemental analysis, IR spectroscopy, TG, and single‐crystal X‐ray analysis. Complex 1 is reported as the first cage‐like cluster constructed by four nitrate anions bridging two [2+2] macrocycles. A blue luminescent emission and luminescent enhancement effect are observed in complex 1 . |
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| Keywords: | Cage‐like complexes Flexible bidentate ligand Silver Crystal structure |
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