Solvothermal Synthesis,Crystal Structure,and Strong Luminescence of the First Organic‐Templated Europium Sulfate Chloride |
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| Authors: | Wanli Zhou Lei Chen Yan Xu |
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| Affiliation: | 1. College of Chemistry, Tonghua Normal University, Tonghua, 134002, P. R. China;2. College of Chemistry and Chemical Engineering, State Key Laboratory of Materials‐Oriented Chemical Engineering, Nanjing University of Technology, Nanjing, 210009, P. R. China |
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| Abstract: | ![]()
The first organic amine templated europium sulfate chloride [C6N4H22]0.5Cl[Eu(SO4)2 · H2O] ( 1 ) was synthesized solvothermally and structurally characterized by single‐crystal X‐ray diffraction, IR spectroscopy, TGA, and ICP. Crystal analyses of compound 1 shows a novel inorganic layer constructed from [–Eu–O–S–O–]n chains. The adjacent chains are connected by sharing the bridging SO42– groups to generate eight‐membered rings. The very strong luminescence in the red light region indicates compound 1 is an excellent candidate for red fluorescent materials. |
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| Keywords: | Solvothermal syntheses Europium sulfate chloride Luminescence |
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