One-step synthesis of phenol by O- and OH- emission material |
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| Authors: | Dong Ting Li Jiang Huang Fan Wang Lian Tu Jing Torimoto Yoshifumi Sadakata Masayoshi Li Quanxin |
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| Institution: | Department of Chemical Physics, BCL Lab, University of Science & Technology of China, Hefei, Anhui, P.R. China 230026. |
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| Abstract: | A novel approach to the direct synthesis of phenol from benzene was obtained with high benzene conversion (30%) and phenol selectivity (approximately 90%) by using a microporous material Ca24Al28O64]4+.4O-(C12A7-O-) as catalyst with oxygen and water; active O- and OH- anions are proposed to play important roles in the formation of phenol by hydroxylating the aromatic ring of benzene. |
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