| 表面修饰乙烯－乙烯醇共聚物膜的“原地”聚离子复合化及其若干性能 |
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| 引用本文： | 张军,王大力,刘新三,李福绵.表面修饰乙烯－乙烯醇共聚物膜的“原地”聚离子复合化及其若干性能[J].高分子学报,1994,0(3):379-384. |
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| 作者姓名： | 张军 王大力 刘新三 李福绵 |
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| 作者单位： | 天津市合成材料研究所; 北京大学化学系 |
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| 摘 要： |
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| 关 键 词： | 聚离子复合物 共聚物 乙烯 乙烯醇 |
| 收稿时间： | 1993-08-06 |
IN SITU POLYIONIC COMPLEXATION OF SURFACE-MODIFIED ETHYLENE-VINYL ALCOHOL COPOLYMER MEMBRANE AND ITS SOME PROPERTIES |
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| ZHANG Jun,WANG Da-li,LIU Xin-san,LI Fu-mian.IN SITU POLYIONIC COMPLEXATION OF SURFACE-MODIFIED ETHYLENE-VINYL ALCOHOL COPOLYMER MEMBRANE AND ITS SOME PROPERTIES[J].Acta Polymerica Sinica,1994,0(3):379-384. |
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| Authors: | ZHANG Jun WANG Da-li LIU Xin-san LI Fu-mian |
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| Institution: | Tianjin Municipal Synthetic Materials Research Institute; Tianjin; 300220; Department of Chemistry; Peking University; Beijing; 100871 |
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| Abstract: | he ethylene-vinyl alcohol copolymer membrane with polyionically complexationalized layer has been prepared by in situ polyionic complexation from cationically modified surface of EVAL membrane and phosphorylated EVAL aqueous solution, which can be considered as a feasible route to modify the surface of membrane for improving the properties , and which is a way to avoid the using of shielding solvent for the processing of polygonic complexes. The condition for the phosphorylation of EVAL has been studied. The effect of the chemical composition of the polyionic complex membrane on the contact angle, water con-tent,mechanical and thermal properties,as well as blood compatibility have been investigated. |
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