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Transesterification of dimethyl oxalate with phenol over Ti-containing phosphate catalysts
Authors:Guoming Zhao  Xiaomei Zhu  Zhenlu Wang  Gang Liu  Yan Liu  Mingjun Jia and Wenxiang Zhang
Institution:(1) Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Changchun, 130021, P. R. China
Abstract:The transesterification of dimethyl oxalate (DMO) with phenol is studied on various Ti-containing phosphate (Ti-P-O) catalysts. The weak acid-base characteristics of Ti-P-O catalysts are responsible for the high activity and selectivity to methyl phenyl oxalate (MPO) and diphenyl oxalate (DPO).
Keywords:Transesterification  dimethyl oxalate  methylphenyl oxalate  diphenyl oxalate
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