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Isothermal Photo Differential Scanning Calorimetry. Crosslinking polymerization of multifunctional monomers in presence of visible light photoinitiators |
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| Authors: | Jakubiak J. Sionkowska A. Lindén L.-Å. Rabek J. F. |
| Affiliation: | (1) Department of Chemistry, Jagiellonian University, Ingardena 3, PL-30 060 Cracow, Poland;(2) Department of Chemistry, Copernicus University, Gagarina 8, PL 87-100 Torun, Poland;(3) Polymer Research Group, Department of Dental Biomaterial Science, Karolinska Institute, Box 4064, S-141 04 Huddinge, Stockholm, Sweden;(4) Department of Chemistry and Chemical Engineering, Technical and Agricultural University, Seminaryjna 3, 85-326 Bydgoszcz, Poland |
| Abstract: | The effect of photoinitating (camphorquinone/amines) system concentration and sample thickness on the photopolymerization of triethyleneglycol dimethacrylate/2-hydroxypropyl methacrylate has been investigated. The rate of photopolymerization reaches a maximum and then decreases as the concentration of photoinitiating system increases. This effect has been intepreted as inner filter effect. This revised version was published online in July 2006 with corrections to the Cover Date. |
| Keywords: | photo-DSC photoinitiating systems photopolymerization |
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