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The growth mechanism and supercapacitor study of anodically deposited amorphous ruthenium oxide films
Authors:VD Patake  SM Pawar  VR Shinde  TP Gujar  CD Lokhande  
Institution:aThin Film Physics Laboratory, Department of Physics, Shivaji University, Kolhapur-416004, Maharashtra, India;bHydrogen Energy Research Center, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul 130-650, Republic of Korea
Abstract:In the present study, ruthenium oxide (RuO2) thin films were deposited on the stainless steel (s.s.) substrates by anodic deposition. The nucleation and growth mechanism of electrodeposited RuO2 film has been studied by cyclic voltammetry (CV) and chronoamperometry (CA). The deposited films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and energy dispersive analysis by X-rays (EDAX) for structural, morphological, and compositional studies. The electrochemical supercapacitor study of ruthenium oxide thin films have been carried out for different film thicknesses in 0.5 M H2SO4 electrolyte. The highest specific capacitance was found to be 1190 F/g for 0.376 mg/cm2 film thickness.
Keywords:Anodic deposition  Ruthenium oxide  Cyclic voltammetry  Supercapacitor
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