Understanding the regioselectivity in Scholl reactions for the synthesis of oligoarenes |
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Authors: | Danz Michael Tonner Ralf Hilt Gerhard |
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Affiliation: | Fachbereich Chemie, Hans-Meerwein-Str., 35043 Marburg, Germany. |
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Abstract: | A short reaction sequence leads to oligoarene derivatives utilising a regioselective Scholl reaction for the unprecedented cyclisation to the mono-functionalised oligoarene under methanol elimination. Quantum-chemical investigations reveal the reason for the remarkably high regioselectivity. |
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