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Understanding the regioselectivity in Scholl reactions for the synthesis of oligoarenes
Authors:Danz Michael  Tonner Ralf  Hilt Gerhard
Affiliation:Fachbereich Chemie, Hans-Meerwein-Str., 35043 Marburg, Germany.
Abstract:A short reaction sequence leads to oligoarene derivatives utilising a regioselective Scholl reaction for the unprecedented cyclisation to the mono-functionalised oligoarene under methanol elimination. Quantum-chemical investigations reveal the reason for the remarkably high regioselectivity.
Keywords:
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